What is temperature it is more important than concentration of chloride and anything higher than room temperature higher is worse. It can lead to unexpected sudden failure of normally ductile metal alloys subjected to a tensile stress, especially at elevated temperature. Chloride stress corrosion cracking clscc is one the most common reasons why austenitic stainless steel pipework and vessels deteriorate in the chemical processing and petrochemical industries. Oct 08, 20 thermowells can breathe in atmospheric moisture. Scc is often associated with chlorides, but can also occur with caustics and other corrosive media. Thermowells can breathe during normal operation as vessels heat up and cool down, drawing in the external atmosphere through non gas tight. Chloride stress corrosion cracking clscc is a type of stress corrosion cracking scc and is one of the most well known forms of scc in the refining and chemical processing industries. This form of corrosion is controlled by maintaining low chloride ion and oxygen content in the environment and use of lowcarbon steels. With regard to the safe temperature for carbon steel, the reader should look at the curve in figure 1. It is thought to start with chromium carbide deposits along grain boundaries that leave the metal open to corrosion. Introduction stress corrosion cracking scc of austenitic 304 stainless steel in chloride environment is a common problem in industries. Chloride stress corrosion cracking in austenitic stainless. It is difficult to control the temperature, while changing pipe material or eliminating residual stresses associated with welding and forming the pipework is costly and incurs plant downtime.
The most common type of stress corrosion cracking in stainless steels occurs in chloride environments, which will be the focus of this discussion. Sensor requirements for detection and characterization of. The effect of salt loading on chloride induced stress corrosion cracking in 304 l was studied at atmospheric pressure. Overstressed ubends of types 304 and 347 stainless steels were exposed to water containing chloride ions to determine the susceptibility of these steels to stress corrosion cracking between the temperatures of 165 f and 200 f. As its name suggests, scc takes the form of a network of cracks that eventually will lead to sudden, catastrophic failure in your tanks. Stainless steel is a family of alloys of which some members are susceptible to chloride induced stress corrosion cracking, that may cause sudden, unexpected fracture. This mode of attack is termed stress corrosion cracking scc. Chloride oxygen stress corrosion cracking mechanisms of austenitic chromiumnickel steels in high purity water at 250 to 350 c over a wide range of stress levels is reported. Chloride induced stress corrosion cracking of stainless.
Chloride stress corrosion cracking in austenitic stainless steel chloride stress corrosion cracking clscc is one of the most common reasons why austenitic stainless steel pipework and vessels deteriorate in the chemical processing and petrochemical industries. Chloride stress corrosion cracking and 316 stainless steel. Ricker, national institute of standards and technology stresscorrosion cracking scc is a term used to describe service failures in engineering materials that occur by slow, environmentally induced crack propagation. Essentially clscc involves a combination of the electrochemistry of metal dissolving over a highly localised area, i. Effect of plastic deformation induced by cold rolling or surface machining on the susceptibility to chloride induced stress corrosion cracking at ambient temperature of 304l austenitic stainless. Intergranular stress corrosion cracking of welded steel twi. Clscc chloride stress corrosion cracking mechanism china. Intouetion table 2 stainless steel alloys such as types 304 and typical mechanical properties per astm a240 316 are very susceptible to chloride stress room type 304 type 316 al6xn corrosion cracking. On the stress corrosion cracking and hydrogen embrittlement. The actual pitting corrosion phenomenon is shown on propeller shaft of high speed craft, and the pit depth was measured with dial. What is the maximum chloride in ppm that can be allowed in.
Article pdf available in materials performance 194. Crevice corrosion tends to be of greatest significance to components built of highly corrosion resistant superalloys and operating with the purestavailable water chemistry. Three underlying factors must be present to cause scc. Stress corrosion cracking of sensitized type 304 stainless. Chloride stress corrosion cracking inspectioneering. Chloride scc is clearly the bane of austenitic stainless steels and one of the main reasons they are not the miracle cure for many corrosion problems. Recently, i read that austenitic stainless steels may suffer from external chloride induced stress corrosion cracking cscc when exposed to a combination of tensile stresses, chlorides, water, oxygen, and a temperature threshold. If you you have temperatures above 150f,you could have stress corrosion cracking of 316 although unlikely below 200 f. Chloride corrosion of carbon steel pipe engineering stack. Developing field test procedures for chloride stress corrosion. For example, chloride stress corrosion cracking of austenitic stainless steel has been experienced in hotwater jacketed pipes carrying molten chocolate in the food industry.
In all cases of failure by stress corrosion cracking, the following three factors must be present. Chloride stress corrosion cracking cscc is a type of intergranular corrosion. The use of 316l would be more resistant to crevice corrosion attack. Austenitic stainless steels chloride induced stress. Chloride stress corrosion cracking of aisi 316 stainless steel downhole pressure memory gauge cover. Stress corrosion cracking is the cracking of a susceptible metal under the mixed. Pdf stress corrosion cracking of austenitic stainless. A precursor of stress corrosion cracking in chloride bearing environments is pitting corrosion, occurring if the stainless steel is not sufficiently resistant to pitting. The effect of salt loading on chlorideinduced stress corrosion cracking in 304 l was studied at atmospheric pressure. The stress corrosion cracking scc and hydrogen embrittlement he behaviors for types 304, 310, and 316 austenitic stainless steels were investigated in boiling saturated magnesium chloride solutions using a constant load method under different conditions including test temperature, applied stress. Therefore, the scc concerns for spent fuel storage canisters identified in a november 2004 presentation by nuclear and. Chloride induced stress corrosion cracking of stainless steel.
A precursor of stress corrosion cracking in chloridebearing environments is pitting corrosion, occurring if the stainless steel is not sufficiently resistant to pitting. These investigations would suggest the addition of these anions to have an inhibiting effect in pitting of stainless steels. Chlorideinduced stress corrosion cracking of 316 stainless. Chloride stress corrosion cracking in austenitic stainless steel. If this is a potable water as described,there is no reason to consider anything but carbon or galvanized steel. Behaviour of stress corrosion cracking of austenitic stainless. Although no stainless steel grade is totally immune. Pitting corrosion of a stainless steel is illustrated in the figure 1. The use of this stainless steel grade in chloride containing environments is not normally recommended unless they are carefully selected, their heat treatment is carefully specified. Stress corrision cracking is a relatively rare form of corrosion, which requires a specific combination of tensile stress, temperature and corrosive species, often the chloride ion, for it to occur. Stress corrosion cracking scc is a common issue with many specialty alloys. Chloride stress corrosion cracks were also found at the corrosion sites. Components under an applied or residual stress can deteriorate further by stress corrosion cracking in these conditions.
Scc is known as an insidious form of corrosion failure and it results in a significant drop in the mechanical strength only with little metal loss. This limits the usefulness of austenitic stainless steel for containing. Why are austenitic stainless steels more susceptible to. Chloride stress corrosion cracking and 316 stainless steel beh188 mechanical.
The failure cracks propagated from intergranular pickling damage to the 12inchthick steel, which was sensitized during initial fabrication. Aisi 304 stainless steel around 8 %10% nickel content. Chloride induced stress corrosion cracking of 316 stainless steel oil tube hi everybody, today, i would like to show my case study to you. External chloride stress corrosion cracking ecscc of insulated austenitic stainless steels e. This investigation exposed ubend specimens to various chloride bearing solutions to better define cracking threshold of the n08367 alloy. Corrosion of stainless steel by hot caustic research using solutions of chemically pure caustic sodium hydroxide naoh led to the development of a diagram that attempts to delineate the param eters of concentration and tem perature governing stress corrosion cracking scc of type. It can be detrimental to austenitic stainless steels, one of the main reasons these steels are not considered a cureall for corrosion problems. Deterioration by clscc can lead to failures that have the potential to release stored energy andor hazardous substances. Stress corrosion cracking of an austenitic stainless steel in nitritecontaining chloride solutions r. Supermartensitic stainless steels smss, including both lean grades without molybdenum and high grades with 2% molybdenum, have shown sensitivity to intergranular corrosion or stress corrosion cracking igscc in weld hazs during laboratory testing in chloride. To apply the load on the samples, 316l stainless steel nuts were used. Wet and humid environments containing chloride ions can cause pitting corrosion and crevice corrosion of austenitic stainless steel components. Whenever stainless steel is exposed to chloride concentrations and stress levels, chloride stress corrosion cracking cscc can occur.
Certain austenitic stainless steels and aluminium alloys crack in the presence of chlorides. How to reduce the risk of stress corrosion cracking scc the risk of stress corrosion cracking scc can be minimized through plant and equipment design. This paper described the mechanism of chloride induced stress corrosion cracking of oil tube as a result of improper material selection and lack of maintenance. Chloride stress corrosion cracking cscc takes place when specific. The nitrogen serves to significantly improve the corrosion resistance of the alloy. Most people have seen the spiderwebbed and lightening array type network of highly branched cracks that is common with chloride cracking of sss. Chloride stress corrosion cracking resistance of 6% mo. The mechanism of chloride stress corrosion cracking clscc is complex and the current understanding is discussed in section 5 of this report. The threshold temperature which the stainless steel is essentially immune to external cscc is 60 degc for aisi 316. Chloride stress corrosion is a type of intergranular corrosion and occurs in austenitic stainless steel under tensile stress in the presence of oxygen, chloride ions, and high temperature. If the cl is present as hcl you have a problem that 316 wont solve.
Scc can occur typically in hot water tanks or swimming pools. Stress corrosion cracking in duplex stainless steel. Intergranular stress corrosion cracking caused failure of two type304 stainless steel outlet nozzles in highpurity heavywater moderator service in nuclear reactors. Deterioration by clscc can lead to failures that have the potential to release. The most common environmental exposure condition responsible for scc of stainless steels is the presence of chlorides. Oct 21, 2019 chloride stress corrosion cracking cscc is a type of intergranular corrosion. Solutions containing less than 1 ppm are normally considered safe. Although the n08367 alloy has improved resistance to chloride stress corrosion cracking cscc it is not completely immune to this mode of failure. Why are austenitic stainless steels more susceptible to chloride stress corrosion cracking than ferritic stainless steels. In general, crevice corrosion is of greatest concern for materials which are normally passive metals, like stainless steel or aluminum. Different kinds of corrosion on stainless steel montanstahl. Chloride stress corrosion is a type of intergranular corrosion and occurs in austenitic stainless steel under tensile stress in the presence of oxygen, chloride ions.
One of the most important forms of stress corrosion that concerns the nuclear industry is chloride stress corrosion. The swimming pool atmosphere, due to the use of chlorinebased disinfectants, can be aggressive for the most popular types of stainless steel, like a2 304, 1. Prevention of external chloride stress corrosion cracking of. Stress corrosion cracking the international institute of. Stress corrosion cracking in a brewery paul mueller company. The combination of tensile stress and a specific corrosive environment can crack stainless steels.
Tp304 ss and tp316 ss can occur when water containing chloride is present underneath insulation, external metal skin temperature exceeds approximately 50 c, and there is no surface protection or when the protective coating e. Stress corrosion cracking scc is cracking due to a process involving conjoint corrosion and straining of a metal due to residual or applied stresses. Pitting is simply a breakdown of the chromium oxide layer followed by localised corrosion that produces pits, which may cause perforation of a vessel. Stainless steels are more resistant to general corrosion compared with carbon steel. The stress corrosion cracking scc and hydrogen embrittlement he behaviors for types 304, 310, and 316 austenitic stainless steels were investigated in boiling saturated magnesium chloride solutions using a constant load method under different conditions including test temperature, applied stress, and sensitization. In austenitic stainless steel, the main forms of corrosion are pitting and stress corrosion cracking caused by chlorides. Your tanks are the core of your brewery, so it is important to understand what scc is, what causes it, and what to do when your tanks suffer from this type of damage. Stress corrosion cracking of insulating jackets often results from airborne salts in coastal regions. Chloride stress corrosion involves selective attack of a metal along its grain boundaries. The probability of failure and the speed of crack propagation are governed by the temperature of the stainless steel and the chloride concentration at the metal surface. In aqueous chloride environments austenitic stainless steels and many nickel based alloys are common to perform poorly. In this case, the most fashion of failure mode in ss is present. It occurs in austenitic stainless steel under tensile stress in the presence of oxygen, chloride ions and high temperature.
This paper presents a fusion welding process that was developed for snf canister repair. Lets discuss the concept of stress corrosion cracking and what it entails, and how it relates to duplex. Prevention of external chloride stress corrosion cracking. Chloride stress corrosion cracking of austenitic stainless. Duplex stainless steel has become more popular for its combination of strength and affordability. The use of a duplex stainless steel with molybdenum such as stainless alloys 2205 or 2507 would resist crevice corrosion and stress corrosion cracking. That can make swageloks engineered solutions for installations exposed to seawater both corrosionresistant and costeffective. Stress corrosion cracking facts and how to reduce the risk. However, the growth and propagation of a crack is widely affected by temperature and less affected by chloride concentration and ph. This article describes the susceptibility of 316l stainless steel to stress corrosion cracking scc in a nitritecontaining chloride.
Cloride stress of stainless steel fasteners fabory. Scc is highly chemically specific in that certain alloys are likely to undergo scc only when exposed to a small number of chemical environments. Chloride stress corrosion cracking and 316 stainless steel sjones petroleum 20 jul 11 03. Effects of marine environments on stress corrosion. Stress corrosion cracking international institute of. Stress corrosion cracking scc can slowly destroy your brewery equipment without warning.
Chloride stress corrosion cracking clscc is one the most common reasons why austenitic stainless steel pipework and vessels deteriorate in the chemical. Singh raman 1, and wai hoong siew 2 1 department of mechanical and aerospace engineering, monash university, melbourne, victoria 3800, australia 2 mechanical engineer, ibm australia 60 city road melbourne, victoria 3006 australia. Integral to johns manville thermo1200 and to sproule wr1200 is xox corrosion inhibitor, a distinctive formula and process that inhibits corrosion to the outside surfaces of pipe and equipment, especially stress corrosion cracking of austenitic stainless steel. The initiation of crack is more dependent on chloride concentration but less dependent on temperature.
Stress corrosion cracking of an austenitic stainless steel in. Stress relieved samples were uniaxially prestrained to 5% and were loaded with nine levels of mgcl 2, investigating cl. Chloride scc is clearly the bane of austenitic stainless steels and one of the main reasons they are not the miraclecure for many corrosion problems. Stress corrosion cracking scc is the growth of crack formation in a corrosive environment. Earlier duplex alloys have had moderate resistance to general corrosion and chloride stress corrosion cracking, but suffered a substantial loss of properties when used in the aswelded condition. The potential for stress corrosion cracking scc of welded stainless steel interim storage containers for spent nuclear fuel snf has been identified as a high priority data gap. There is a synergistic relationship between dissolved oxygen and the chloride level.
Stress corrosion cracking of an austenitic stainless steel. Failure analysis of corrosion on stainless steel fasteners. Chloride stress corrosion cracking initiates from sites of localized pitting or crevice corrosion. Not only can duplex stainless steel hold up reliably through trauma impact, but through corrosion as well. Scc is a form of corrosion that occurs in nearly all alloys, including the grades of stainless steel commonly used in brewery equipment types 304, 304l, 316, and 316l. While no stainless steel can be completely immune, swageloks alloy 316 stainless steel fittings have performed exceptionally well in testing.